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In the electrolyte of an electrochemical cell, current is carried by electrons moving from the anode to the cathode.

A) True
B) False

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What product forms at the cathode during the electrolysis of molten lithium iodide?


A) Li+(l)
B) Li(l)
C) I-(l)
D) I2(g)
E) I3-(l)

F) None of the above
G) B) and D)

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Select the incorrect statement relating to the corrosion of iron in air.


A) Fe2+ is formed in the anodic region.
B) O2 is oxidized in the cathodic region.
C) Electrons travel through the iron metal between the anodic and cathodic regions.
D) Moisture provides a pathway for ions to migrate.
E) Rust is a hydrated form of iron(III) oxide.

F) C) and D)
G) A) and B)

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In the electrolyte of an electrochemical cell, current is carried by anions moving toward the anode and cations moving in the opposite direction.

A) True
B) False

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Which one of the following statements relating to the glass electrode is correct?


A) The glass electrode detects hydrogen gas.
B) The glass of a glass electrode serves to conduct electrons.
C) When pH is measured, only a single electrode, the glass electrode, need be used.
D) The potential of the glass electrode varies linearly with the pH of the solution.
E) None of these choices are correct.

F) All of the above
G) A) and C)

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D

In the electrolysis of aqueous potassium nitrate using inert electrodes, which one of the following species is oxidized?


A) potassium ion
B) nitrate ion
C) water
D) oxygen
E) hydronium ion

F) None of the above
G) B) and E)

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The line notation, Pt | H2(g) | H+(aq) || Cu2+(aq) | Cu(s) , indicates that


A) copper metal is a product of the cell reaction.
B) hydrogen gas (H2) is a product of the cell reaction.
C) Cu is the anode.
D) Pt is the cathode.
E) Cu2+ is the reducing agent.

F) A) and B)
G) A) and C)

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Consider the nonaqueous cell reaction 2Na(l) + FeCl2(s) Consider the nonaqueous cell reaction 2Na(l)  + FeCl<sub>2</sub>(s)    2NaCl(s)  + Fe(s)  For which E°<sub> cell</sub> = 2.35 V at 200°C. ΔG° at this temperature is A)  453 kJ. B)  -453 kJ. C)  907 kJ. D)  -907 kJ. E)  None of these choices are correct. 2NaCl(s) + Fe(s) For which E° cell = 2.35 V at 200°C. ΔG° at this temperature is


A) 453 kJ.
B) -453 kJ.
C) 907 kJ.
D) -907 kJ.
E) None of these choices are correct.

F) All of the above
G) B) and C)

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The voltaic cell made up of cobalt, copper, and their M2+ ions, has E°cell = 0.62 V. If E° of the cathode half-cell is 0.34 V, what is E° of the anode half-cell? Cu2+(aq) + Co(s) → Cu(s) + Co2+(aq)


A) -0.28 V
B) -0.96 V
C) 0.28 V
D) 0.96 V
E) None of these choices are correct.

F) B) and C)
G) None of the above

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When metal A is placed in a solution of metal ions B2+, a reaction occurs between A and B2+, and metal ions A2+ appear in the solution. When metal B is placed in acid solution, gas bubbles form on its surface. When metal A is placed in a solution of metal ions C2+, no reaction occurs. Which of the following reactions would not occur spontaneously?


A) C(s) + 2H+(aq) → H2(g) + C+(aq)
B) C(s) + A2+(aq) → A(s) + C2+(aq)
C) B(s) + C2+(aq) → C(s) + B2+(aq)
D) A(s) + 2H+(aq) → H2(g) + A2+(aq)
E) B(s) + 2H+(aq) → H2(g) + B2+(aq)

F) A) and E)
G) B) and E)

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When the following redox equation is balanced with smallest whole number coefficients, the coefficient for the iodide ion will be I-(aq) + NO3-(aq) → NO(g) + I2(s) (acidic solution)


A) 2.
B) 3.
C) 6.
D) 8.
E) None of these choices are correct.

F) All of the above
G) A) and B)

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Consider the following balanced redox reaction Mn2+(aq) + S2O82-(aq) + 2H2O(l) → MnO2(s) + 4H(aq) + 2SO42-(aq) Which of the following statements is true?


A) Mn2+(aq) is the oxidizing agent and is reduced.
B) Mn2+(aq) is the oxidizing agent and is oxidized.
C) Mn2+(aq) is the reducing agent and is oxidized.
D) Mn2+(aq) is the reducing agent and is reduced.
E) Manganese does not change its oxidation number in this reaction.

F) B) and D)
G) B) and E)

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What mass of copper will be deposited when 18.2 A are passed through a CuSO4 solution for 45.0 minutes?


A) 16.2 g
B) 33.4 g
C) 40.6 g
D) 81.3 g
E) 163 g

F) None of the above
G) A) and C)

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Chromium metal is electroplated from acidic aqueous solutions containing the dichromate ion, Cr2O72-. What is the minimum time needed to plate out 10.0 g of chromium metal from such a solution, if the current is 50.0 A?


A) 6.2 minutes
B) 12.4 minutes
C) 18.6 minutes
D) 24.7 minutes
E) 37.1 minutes

F) D) and E)
G) A) and C)

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C

A salt bridge provides a path for electrons to move between the anode and cathode compartments of a voltaic cell.

A) True
B) False

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The line notation, Al(s) | Al3+(aq) || Co2+(aq) | Co(s) , indicates that


A) Co is the reducing agent.
B) Co2+ ions are oxidized.
C) Al is the reducing agent.
D) Al3+ is the reducing agent.
E) aluminum metal is the cathode.

F) A) and B)
G) A) and C)

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Which, if any, of the following metals would be capable of acting as a sacrificial anode when used with iron pipe? E°Fe = -0.44 V; all E° values refer to the M2+/M half-cell reactions.


A) copper, Cu, E° = 0.15 V
B) cobalt, Co, E° = -0.28 V
C) chromium, Cr, E° = -0.74 V
D) tin, Sn, E° = -0.14 V
E) None of these metals would be capable of acting as a sacrificial anode with iron.

F) C) and D)
G) A) and E)

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The redox reaction of peroxydisulfate with iodide has been used for many years as part of the iodine clock reaction which introduces students to kinetics. If E°cell = 1.587 V and E° of the cathode half-cell is 0.536 V, what is E° of the anode half-cell? S2O82-(aq) + 2H+ + 2I-(aq) → 2HSO4-(aq) + I2(aq)


A) -1.051 V
B) -2.123 V
C) 1.051 V
D) 2.123 V
E) None of these choices are correct.

F) None of the above
G) A) and E)

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What is the E°cell for the cell represented by the combination of the following half-reactions? ClO4(aq) + 8H(aq) + 8e What is the E°<sub>cell</sub> for the cell represented by the combination of the following half-reactions? ClO<sub>4</sub>(aq)  + 8H(aq)  + 8e   Cl-(aq)  + 4H<sub>2</sub>O(l)  E° = 1.389 V VO<sub>2</sub>(aq)  + 2H(aq)  + e<sup>-</sup> j   VO(aq)  + H<sub>2</sub>O(l)  E° = 0.991 V A)  -0.398 V B)  -2.380 V C)  0.398 V D)  2.380 V E)  None of these choices are correct. Cl-(aq) + 4H2O(l) E° = 1.389 V VO2(aq) + 2H(aq) + e- j What is the E°<sub>cell</sub> for the cell represented by the combination of the following half-reactions? ClO<sub>4</sub>(aq)  + 8H(aq)  + 8e   Cl-(aq)  + 4H<sub>2</sub>O(l)  E° = 1.389 V VO<sub>2</sub>(aq)  + 2H(aq)  + e<sup>-</sup> j   VO(aq)  + H<sub>2</sub>O(l)  E° = 0.991 V A)  -0.398 V B)  -2.380 V C)  0.398 V D)  2.380 V E)  None of these choices are correct. VO(aq) + H2O(l) E° = 0.991 V


A) -0.398 V
B) -2.380 V
C) 0.398 V
D) 2.380 V
E) None of these choices are correct.

F) C) and D)
G) All of the above

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What mass of silver will be formed when 15.0 A are passed through molten AgCl for 25.0 minutes?


A) 0.419 g
B) 6.29 g
C) 12.6 g
D) 25.2 g
E) 33.4 g

F) B) and C)
G) A) and B)

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D

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